The gas-phase equilibrium reaction between fluorobenzene and chlorobenzene and their conjugate bases was studied by Fourier transform ion cyclotron resonance spectrometry in order to reconcile conflicting experimental results obtained using different techniques. The results of a large number of meas
ChemInform Abstract: Gas-Phase Acidities of Aryldimethylsilanes.
β Scribed by Maki Irie; Kiyoshi Kikukawa; Nobujiro Shimizu; Masaaki Nishima
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The acidity of aliphatic alcohols in gas phase is reinvestigated with the aim at establishing the simplest, yet reliable, level of description to be used for the solute in a solution-phase acidity calculation. It is shown that a procedure which includes only the differential correlation effects aris
AM1 and ab initio calculations were performed for molecular glucopyranose and its alkoxy anions. Minimum energy conformers were found for both the a-and b-anomers of molecular glucose and each of the corresponding deprotonated species. Cooperative hydrogen bonding towards the charge site was observe
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The gas-phase acidities βG acid (298 K) of the sulfanes H 2 S n may be compared to those of other strong BrΓΈnsted acids like gaseous HNO 2 (1396), HCl (1371), and HBr (1332). The (n = 1-4) have been calculated by ab initio molecular orbital theory using the G2 and G2(MP2) methods, which were monoani
The kinetic method was applied to the estimation of the gas-phase acidity of urea by generating proton-bound dimeric anions comprised of urea and various reference compounds using negative ion desorption chemical ionization and examining their dissociation upon collision in a triple quadrupole mass