Gas-phase acidities of alcohols
โ Scribed by Brauman, John I.; Blair, Larry K.
- Book ID
- 126236010
- Publisher
- American Chemical Society
- Year
- 1970
- Tongue
- English
- Weight
- 922 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The acidity of aliphatic alcohols in gas phase is reinvestigated with the aim at establishing the simplest, yet reliable, level of description to be used for the solute in a solution-phase acidity calculation. It is shown that a procedure which includes only the differential correlation effects aris
The gas-phase acidities of several ฮฑ, ฯ-alkanediols were measured with the equilibrium method in an ion cyclotron resonance spectrometer. The values obtained imply cyclization of the structures via an intramolecular hydrogen bond. The results are in quantitative disagreement with those obtained by t