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Gas chromatographic enantiomer separation with modified cyclodextrins: Carboxylic acid esters and epoxides

✍ Scribed by König, Wilfried A. ;Gehrcke, Bärbel

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
477 KB
Volume
16
Category
Article
ISSN
0935-6304

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✦ Synopsis

Abstract

The wide range of application of 2,6‐di‐O‐methyl‐3‐O‐pentyl‐β‐and y‐cyclodextrins is demonstrated by the resolution of the enantiomers of the methyl esters of chiral carboxylic acids: α and β hydroxy acids with up to 18 carbon atoms, hydroxy di‐ and tricarboxylic acids, and alkyl/aryl‐substituted carboxylic acid methyl esters, including the plant hormone abscisic acid, insect juvenile hormones, and some non‐steroidal anti‐inflammatory drugs can be resolved with generally large separation factors. The new cyclodextrin derivatives also exhibit high selectivity for epoxides.

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