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Enantiomer separation with capillary gas chromatography columns coated with cyclodextrins. Part I: Separation of enantiomeric 2-substituted propionic acid esters and some lower alcohols with permethylated β-cyclodextrin

✍ Scribed by Venema, A. ;Tolsma, P. J. A.


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
262 KB
Volume
12
Category
Article
ISSN
0935-6304

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✦ Synopsis


The applicability of permethylated P-cyclodextrin as an enantioselective stationary phase for capillary gas chromatography has been investigated. Attention has been paid to its phase transitions in a temperature range of 40-2OO0C. The enantiomer separation of 2-substituted propionates and some lower alcohols illustrates the pronounced selectivity of the permethylated p-cyclodextrin relative to molecular geometry.