The PCI mass spectrum obtained with methane as reagent gas yielded a molecular ion peak at m/z 217 (M + 1) as the base peak. Other characteristic peaks were also discernible at m/z 245 (M + 29) and 257 (M + 41) (Figure 3B). Selective ion monitoring (SIM) could be used to quantify 1.0 ng of the deriv
Gas chromatographic analysis of estrogens from pregnant mares' urine using glass capillary columns
β Scribed by Zweig, J. S. ;Roman, R. ;Hagerman, W. B. ;VandenHeuvel, W. J. A.
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 239 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0935-6304
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β¦ Synopsis
Abstract
Glass capillary columns coated with OVβ225 and Silar 10C were used to analyze estrogens (as their trimethylsilyl derivatives) present in pregnant mares' urine. Such columns provide better resolution in a shorter time than the corresponding packed columns, as exemplified by the separation of estrone from equilin.
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