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GaI3 Catalyzed Nucleophilic Addition of Allyltrimethylsilane to Aldehydes.

✍ Scribed by Peipei Sun; Yufang Xian; Yaping Xiao


Book ID
101961228
Publisher
John Wiley and Sons
Year
2004
Weight
21 KB
Volume
35
Category
Article
ISSN
0931-7597

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The effect of hydrogen bonding between nitrones and urea derivatives in the nucleophilic addition reaction was examined. Thioureas bearing an electron-withdrawing group on an aromatic ring, behave like Lewis acid to promote the addition of TMSCN and ketene silyl acatals to various nitrones and aldeh