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Catalytic enantioselective nucleophilic addition of ynamides to aldehydes

✍ Scribed by Cook, Andrea M.; Wolf, Christian

Book ID
121495787
Publisher
Royal Society of Chemistry
Year
2014
Tongue
English
Weight
755 KB
Volume
50
Category
Article
ISSN
1359-7345

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Catalytic enantioselective addition of d
Catalytic enantioselective addition of diethylzinc to (hetero)aromatic aldehydes
✍ Irina Iovel; GΓΌnther Oehme; Edmunds Lukevics πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 92 KB πŸ‘ 2 views

The asymmetric alkylation with diethylzinc of five heterocyclic aldehydes and benzaldehyde (for comparison) has been studied in the presence of two optically active amino alcohols: (S)-2-amino-1-butanol (AB) and (1S,2R)-N,Ndibutylnorephedrine (DBNE). A number of chiral (hetero)aromatic secondary alc