The crystal structures of three dinuclear diperoxo compounds have been determined from single-crystal X-ray diffraction data. All title compounds crystallize as yellow needle-shaped crystals in the triclinic space group P 1(2). ( 1 where 2-MepyH denotes 2-methylopyridine, crystallize with a = 6.733
✦ LIBER ✦
Further comments on the lability of M2(O2CR)4 complexes and structural characterization of [Bu4nN]2+[Rh8(O2CBut)16(O2CMe)2(toluene)2]2−
✍ Scribed by Malcolm H. Chisholm; Kirsten Folting; Kamdasamy G. Moodley; Jodi E. Wesemann
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 188 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0277-5387
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A mixture of Na,MO,, M(CO),, FeC1,.6 H,O, and (EtCO),O was heated at 120 ' C to produce the heterooctanuclear clusters Na,Fe,[M,O,-(O,CEt),], (M = Mo, 1; W, 2). The bioxo-capped clusters Na[M,O,(O,CEt),] (M, = MOW,, W,) were treated with Fe-(CO),, Cr(CO),, and Mo(CO), in (EtCO),O at 120°C to afford