We are currently seeking models for the various oxidation levels (S, states; n = -1 through 4) of the photosynthetic water oxidation center (WOC), to assist in the elucidation of its nature and mode of action.1'l The WOC requires four Mn atoms for activity, and these are 0x0-bridged and ligated by 0
Synthesis and characterization of Mn4O2(O2CR)6Cl2(py)4 and [Mn4O2(O2CPh)6(Et2mal)(H2O)]2−2 (R = 3,5-F2-Ph). Variations on the [Mn4O2] butterfly ligand set and potential biological relevance.
✍ Scribed by Michael W. Wemple; William E. Streib; John C. Huffman; George Christou
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 82 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0162-0134
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packed structures was further extended by Goodenough's group to 3-D materials with the spinel structure (3). It was Lithium manganospinels belonging to the LiMn 2 O 4 -Li 2 Mn 4 O 9 -Li 4 Mn 5 O 12 system were prepared by solid-state reac-shown that lithium could be intercalated into the spinels tio