Functionalized cyclopentadienyl rhodium(iii) bipyridine complexes: synthesis, characterization, and catalytic application in hydrogenation of ketones
โ Scribed by Wang, Wan-Hui; Suna, Yuki; Himeda, Yuichiro; Muckerman, James T.; Fujita, Etsuko
- Book ID
- 125530796
- Publisher
- Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 483 KB
- Volume
- 42
- Category
- Article
- ISSN
- 1477-9226
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## Abstract Mixed Nโheterocyclic carbeneโsubstituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free Nโheterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru
Eight zirconocene dichloride complexes are described that contain an alkyl or silylalkyl substituent with a fluorenyl end group on the cyclopentadienyl ring. Also, a bridged cyclopentadienyl indenyl metallocene complex with a fluorenyl terminated alkyl substituent is reported. These complexes were a