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A Covalently Immobilized Triphenylphosphine Rhodium Complex: Synthesis, Characterization, and Application in Catalytic Olefin Hydrogenation

✍ Scribed by Lei Wang; Prof. Dr. Mingjun Jia; Dr. Sankaranarayanapillai Shylesh; Thomas Philippi; Dr. Andreas Seifert; Prof. Dr. Stefan Ernst; Dr. Anand Pal Singh; Prof. Dr. Werner R. Thiel

Book ID: 112018864
Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 409 KB
Volume: 2
Category: Article
ISSN: 1867-3880
DOI: 10.1002/cctc.201000133

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## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru