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Synthesis and characterization of new rhodium and iridium complexes with trianisylphosphine, PAn3, and evaluation of their catalytic behavior in the homogeneous hydrogenation of cinnamaldehyde

✍ Scribed by Vanessa R. Landaeta; Francisco López-Linares; Roberto Sánchez-Delgado; Claudio Bianchini; Fabrizio Zanobini; Maurizio Peruzzini


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
921 KB
Volume
301
Category
Article
ISSN
1381-1169

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## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru