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Fully Automated Continuous Flow Synthesis of 4,5-Disubstituted Oxazoles

✍ Scribed by Baumann, Marcus; Baxendale, Ian R.; Ley, Steven V.; Smith, Christoper D.; Tranmer, Geoffrey K.

Book ID: 118174472
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 182 KB
Volume: 8
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol061975c

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## Abstract The rapid synthesis of 2,4‐ and 2,5‐disubstituted oxazoles __via__ metal‐catalyzed cross‐coupling reactions is reported. The 4‐ or 5‐position of the corresponding 4‐ or 5‐halogenated 2‐butylthiooxazoles was successfully functionalized __via__ Suzuki–Miyaura, Sonogashira and Stille cross