Fullerenols Revisited as Stable Radical Anions
β Scribed by Husebo, Lars O.; Sitharaman, Balaji; Furukawa, Ko; Kato, Tatsuhisa; Wilson, Lon J.
- Book ID
- 119960360
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 524 KB
- Volume
- 126
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract The radical anion of (__E__)βazobenzene, generated from the neutral compound by reaction with potassium mirror in an ethereal solvent, has been fully characterized by its hyperfine data with the use of ESR, ENDOR and TRIPLEβresonance spectroscopy. Assignments of coupling constants to pr
The electrochemical reduction of the carbene 1 reversibly yielded the corresponding radical union 2, which was characterized by ESR measurements. Ab initio calculations provided a better understanding of its structure and stability.