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A stable carbene as π-acceptor electrochemical reduction to the radical anion

✍ Scribed by Dieter Enders; Klaus Breuer; Gerhard Raabe; Jacques Simonet; Ahmed Ghanimi; Hartmut B. Stegmann; J.Henrique Teles

Book ID: 104256858
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 202 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00493-0

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✦ Synopsis

The electrochemical reduction of the carbene 1 reversibly yielded the corresponding radical union 2, which was characterized by ESR measurements. Ab initio calculations provided a better understanding of its structure and stability.

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