✦ LIBER ✦

The radical anion of (E)-azobenzene revisited

✍ Scribed by Urs Buser; Caspar H. Ess; Fabian Gerson

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 343 KB
Volume: 29
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260290715

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✦ Synopsis

Abstract

The radical anion of (E)‐azobenzene, generated from the neutral compound by reaction with potassium mirror in an ethereal solvent, has been fully characterized by its hyperfine data with the use of ESR, ENDOR and TRIPLE‐resonance spectroscopy. Assignments of coupling constants to protons in the individual positions are based on comparison with the spectra of the radical anions of 4,4′‐dideuterio and 2,2′‐dimethyl derivatives. Effects of ^14^N hyperfine anisotropy on ESR spectra and of association with the counter ion K^+^ are briefly discussed.

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