𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ESR study of the 4,4′-dimethoxy azobenzene radical anion

✍ Scribed by R.K. Gupta; S.S. Dua; P.T. Narasimhan; M.V. George

Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
179 KB
Volume
1
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

ESR spectra of 4.4'-dimethoxyazobenzene radical anion, obtained using sodium or lithium metal reduction in tetrahydrofuran.

are presented.

The spectra reveal 'contact' ion-pairs in the sodium case and 'free' anions in thelithium case.

📜 SIMILAR VOLUMES

The radical anion of (E)-azobenzene revi
The radical anion of (E)-azobenzene revisited
✍ Urs Buser; Caspar H. Ess; Fabian Gerson 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 343 KB

## Abstract The radical anion of (__E__)‐azobenzene, generated from the neutral compound by reaction with potassium mirror in an ethereal solvent, has been fully characterized by its hyperfine data with the use of ESR, ENDOR and TRIPLE‐resonance spectroscopy. Assignments of coupling constants to pr

The ESR. Spectrum of the Diphenylcyclopr
The ESR. Spectrum of the Diphenylcyclopropenone Radical Anion
✍ Peter Fürderer; Fabian Gerson; Adolf Krebs 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 German ⚖ 379 KB

## Abstract The ESR. spectrum of the relatively unstable radical anion of diphenylcyclo‐propenone (II) has been observed upon electrolytic reduction of II in __N__,__N__‐di‐methylformamide and 1,2‐dimethoxyethane. Simple MO models account well for the π‐spin distribution and for the restricted rota