An ESR study of the benzocyclooctatetraene radical anion
✍ Scribed by J.R. Dodd
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 224 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
## Abstract Proton‐hyperfine data are reported for the radical anions generated from azulene (1) and its alkyl derivatives 2–11 in 1,2‐dimethoxyethane both ‘chemically’ with K and electrolytically. The alkyl derivatives are 1,3‐dimethyl‐ (2), 5,7‐dimethyl‐ (3), 1,3,5,7‐tetramethyl‐ (4), 2‐methyl‐ (
ESR spectra of 4.4'-dimethoxyazobenzene radical anion, obtained using sodium or lithium metal reduction in tetrahydrofuran. are presented. The spectra reveal 'contact' ion-pairs in the sodium case and 'free' anions in thelithium case. -
## Abstract Radical anions often monocyclic and bicyclic azoalkanes containing the azo group in (__Z__)‐conformation, have been fully characterized by their hyperfine data with the use of ESR, ENDOR, and general‐TRIPLE‐resonance spectroscopy. These azoalkanes are represented by 3,3,5,5‐tetramethyl‐
## Abstract Radical anions of ten monocyclic and bicyclic azoalkanes containing the azo group in (Z)‐conformation, have been fully characterized by their hyperfine data with the use of ESR, ENDOR, and general‐TRIPLE‐resonance spectroscopy. These azoalkanes are represented by 3,3,5,5‐tetramethyl‐1‐p