FTIR spectra of HSCH2CH2SH, CH3SCH2SH, and CH3SSCH3 in argon and nitrogen matrices
โ Scribed by Ying-Sing Li; San Li
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 777 KB
- Volume
- 50
- Category
- Article
- ISSN
- 1386-1425
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๐ SIMILAR VOLUMES
The kinetics of the title reactions were investigated in a discharge flow tube by using laser magnetic resonance detection of HO2. The upper limits for the bimolecular rate constants for the reactions of HO2 with H2S ( k l ) , CH3SH (k2), and CH3SCH3 ( k 3 ) are <3 X <4 X and <5 X cm3 molecule-l s-l
Ab initio calculations at the [QCISD(T)/6-31 +G(Zdf, p)]//MP2/6-31G(d) level have been applied to CH$CH200, a radical which is thought to be important in the atmospheric oxidation of dimethylsulfide. The geometries of CH3SCH200 and the related CI-ISSCH20 radical are similar to other organic radicals