Complex formation of sulfur dioxide with HSCH2CH2SH, CH3SCH2SH, and CH3SSCH3 in argon matrices
β Scribed by San Li; Ying-Sing Li
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 577 KB
- Volume
- 301
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
The kinetics of the title reactions were investigated in a discharge flow tube by using laser magnetic resonance detection of HO2. The upper limits for the bimolecular rate constants for the reactions of HO2 with H2S ( k l ) , CH3SH (k2), and CH3SCH3 ( k 3 ) are <3 X <4 X and <5 X cm3 molecule-l s-l
Some chemical reactions of the triethylammonium salts of 2 are summarized in Scheme 2.
A kinetic study has been made of the gas phase, I,-catalyzed decomposition of (CH&S at 630-650 K. Some I, is consumed initially, reaching a steady-state concentration. The initial major products are CH4 and CH,S together with small amounts of CH3SCHZI, CHSI, HI, and CS2. The initial reaction corresp