From radical?radical association rates to potential-energy parameters: SACM comparison of the reactions H + C7H7? C7H8 and H + CH3? CH4
✍ Scribed by Troe, J.
- Book ID
- 121479444
- Publisher
- Royal Society of Chemistry
- Year
- 1991
- Tongue
- English
- Weight
- 929 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0956-5000
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Charge-changing cross-sections u43, u42 and u4, of C4+ injected into CH, , C2H,, C,H, and n-C4H,, were measured in the energy range 0.7-400 eV u-'. A tandem mass spectrometer system with an ion source of the EBIS type (Mini-EBIS) and a collision cell consisting of an octupole ion beam guide was used
Absolute values of the reaction cross section, CT,, for the title reaction family have been measured by chemiluminescence emission under beam-gas conditions. The uR values diminish as the radical group R increases in size, showing an important overall steric effect. These results are discussed in th