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Direct Dynamics of an Alkoxy Radical (CH 3 O, C 2 H 5 O, and i- C 3 H 7 O) Reaction with an Oxygen Molecule

โœ Scribed by Setokuchi, Osamu; Sato, Masaru


Book ID
127355569
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
301 KB
Volume
106
Category
Article
ISSN
1089-5639

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๐Ÿ“œ SIMILAR VOLUMES


Reactions of alkoxy radicals with O2. I.
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CzH50NO was photolyzed with 366 nm radiation at -48, -22, -2.5, 23, 55, 88, and 120ยฐC in a static system in the presence of NO, 0,, and N,. The quantum yield of CH3CH0, (D{CH3CHO), was measured as a function of reaction conditions. The primary photochemical act is (la) CZHSONO + hv -\* CzH50 + NO an

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n-C3H70N0 was photolyzed with 366 nm radiation at -26, -3,23,55, 88, and 120ยฐC in a static system in the presence of NO, Oz, and N 2 . The quantum yields of C2H5CH0, C z H 5 0 N 0 , and CH3CH0 were measured as a function of reaction conditions. The primary photochemical act is and it proceeds with

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UV absorption spectra of i-&H, and i-C,H70Z radicals have been obtained following pulse radiolysis of Hz/&H6 and H&HdOr mixtures at a total pressure of 1 atm at room temperature. The i-C3H7 spectrum shows two absorption maxima with t( 233 nm) =89Of. 130 M-' cm-' and ~(205 nm) =780+ 120 M-' cm-', res