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Energy Barriers for the Addition of H, ĊH 3 , and Ċ 2 H 5 to CH 2 ═CHX [X = H, CH 3 , OH] and for H-Atom Addition to RCH═O [R = H, CH 3 , Ċ 2 H 5 , n -C 3 H 7 ]: Implications for the Gas-Phase Chemistry of Enols

✍ Scribed by Simmie, John M.; Curran, Henry J.

Book ID
120368777
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
229 KB
Volume
113
Category
Article
ISSN
1089-5639

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✍ P. D. Pacey; J. H. Purnell 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 English ⚖ 468 KB 👁 1 views

Study of n-butane pyrolysis at high temperature in a flow system allows measurement of the sum of the rate constants of the initiation reactions (2) and of the Arrhenius parameters of the reactions Established data for kl/k2 allow estimation of kl for 951'K and this, with recent thermochemical da