Free radical ring-opening polymerization
β Scribed by Bailey, William J.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1985
- Weight
- 641 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0025-116X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Radical emulsion polymerizations of vinylcyclopropanes, 1,1-bis(ethoxycarbonyl)-2-vinylcyclopropane (ECVCP) and 1,1-dichloro-2-vinylcyclopropane (CVCP) were examined. ECVCP underwent soap-free and soap-in emulsion polymerizations satisfactorily to afford the ring-opened polymer in good yields. Polym
Ring-opening radical polymerization has been followed by the flash photolysis method. As a n initiator radical, the arylthiyl radical (ArS') was used; the addition reaction rate constants of ArS' to vinyl monomer containing epoxy-ring such as vinyloxiranes (CH2 = C H C m H 2 ) have been determined a
Free radical ring-opening polymerization of 2-methylene-1,3-dioxepane (MDP) in the presence of 2,2,6,6-tetramethyl-1-piperidinyloxy free radical (TEMPO) has been achieved to afford a chain polyester (PMDP) with di-t-butyl peroxide (DTBP) as an initiator at 125ΠC. The polydispersity of the polymers d