5-Bromopenta-1,3-diene (BPD) was examined as an additionfragmentation chain transfer agent (AFCTA) in the free radical polymerization of methyl methacrylate (MMA). Studies of the kinetics of polymerization in the presence of this compound showed it to be a very e β ective chain transfer agent and tha
Free Radical Initiation Mechanisms in the Polymerization of Methyl Methacrylate and Styrene with 1,1,3,3-Tetramethylbutyl Peroxypivalate: Addition of Neopentyl Radicals
β Scribed by Nakamura, Tomoyuki; Busfield, W. Ken; Jenkins, Ian D.; Rizzardo, Ezio; Thang, San H.; Suyama, Shuji
- Book ID
- 126823249
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 162 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The title compound, the first member of a homologous series of oligomers formed by free radical polymerization of methyl methacrylate initiated by tetraphenylbutanedinitrile, was synthesized and its structure was determined by X-ray diffraction. The longest C--C bond of this molecule measures 1.628
The competitive reactions of cyanoisopropyl radicals with the mixed monomers styrene and acrylonitrile have been investigated using the nitroxide radical trapping technique. When the trap concentration is kept low, second, third, and even fourth generation (in terms of successive monomer addition) c