Effect of Bis(6-methylpyridazinyl)-3,3′-disulfide in the Radical Polymerizations of Styrene and Methyl Methacrylate
✍ Scribed by Eda, Tsunehito; Huang, Chao Yang; Matsubara, Yoshio; Yoshihara, Masakuni; Maeshima, Toshihisa
- Book ID
- 126887627
- Publisher
- Informa UK (Taylor & Francis)
- Year
- 1980
- Tongue
- English
- Weight
- 281 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0022-233X
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The title compound, the first member of a homologous series of oligomers formed by free radical polymerization of methyl methacrylate initiated by tetraphenylbutanedinitrile, was synthesized and its structure was determined by X-ray diffraction. The longest C--C bond of this molecule measures 1.628
## Abstract Three novel iniferter reagents were synthesized and used as initiators for the polymerizations of methyl methacrylate (MMA) and styrene (St) in the presence of copper(I) bromide and __N,N,N__′,__N__″,__N__″‐pentamethyldiethylenetriamine at 90 and 115°C, respectively. All the polymerizat