𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Free-radical addition to olefins of an H2S equivalent: Triphenylsilanethiol

✍ Scribed by Bruno Haché; Yves Gareau

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
210 KB
Volume
35
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

The tr&benyLsnytbiyl dical gcperated dmnally (AIBN-I or pbmdmnicalty in tbe pmsemce ofan olefin yields tbe anti-Vv H$ addua after-by aitltwmacek add (TFA).

📜 SIMILAR VOLUMES

Free radical addition of 1,3,5 - trioxan
Free radical addition of 1,3,5 - trioxan to olefins
✍ I. Rosenthal 📂 Article 📅 1968 🏛 Elsevier Science 🌐 French ⚖ 78 KB

In a recent publication (1) we have reported the light-induced addition of acetals to olefins which led to the corresponding monoalkyl acetal derivatives. We report now the peroxide-induced addition of 1.3,5-trioxan to olefins at elevated temperatures.

ChemInform Abstract: Addition of an Apio
ChemInform Abstract: Addition of an Apiosyl Radical to Activated Olefins - Synthesis of C- Apiosyl Compounds.
✍ M. DRESCHER; F. HAMMERSCHMIDT 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Free radical addition of haloalkanes to
Free radical addition of haloalkanes to polymer bound olefins and its application to the solid-phase synthesis of pyrethroids
✍ H.M.S Kumar; P.Pawan Chakravarthy; M Shesha Rao; P.Sunder Ram Reddy; J.S Yadav 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 306 KB

Polymer bound olefins undergo free radical initiated 1,2-addition when reacted with a variety of haloalkanes. The strategy could be applied successfully to the solid-phase synthesis of dihaloethenylcyclopropane carboxylic acids which are the key fragments of synthetic pyrethroids.