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Na2S2O4-Initiated Free Radical Additions of Polyfluoroalkyl Halides to 4-Pentenamides.

✍ Scribed by Xianjin Yang; Wenjiao Yuan; Song Gu; Xueyan Yang; Fanhua Xiao; Quanshen Shen; Fanhong Wu


Publisher
John Wiley and Sons
Year
2007
Weight
31 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract Perfluoroalkyl iodides were added in very good yields to 1,2‐dialkyl substituted double bonds of e.g. petroselinic acid initiated by lead/copper(II) acetate in methanol and by copper without solvent, respectively. Using the new initiator system lead/copper(II) acetate, we also obtained