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Free Radical Addition and Cyclization Reactions of [2-(4-(S)-Isopropyl-2-oxazoline)-5-phenyl]dialkyltin Hydrides.

✍ Scribed by A. Stepien; A. Petrosyan; M. Wilk; P. Cmoch; L. Rupnicki; K. Stalinski


Publisher
John Wiley and Sons
Year
2005
Weight
23 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract The chiral iridium compounds [IrCl(COE){(__S__)‐PN}] {COE = cyclooctene, PN = (4__S__)‐2‐[2‐(diphenylphosphanyl)phenyl]‐4‐isopropyl‐1,3‐oxazoline, (1)}, [Ir(acac)ClH{(__S__)‐PN}] {Hacac = acetylacetone, (2)} and [Ir{(__S__)‐PN}~2~]A {A = Cl (3a,b); BF~4~ (4a,b); PF~6~ (5a,b)} have been