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FREE RADICAL ADDITION OF CYCLOPENTANE AND CYCLOHEXANE TO FORMALDEHYDE

✍ Scribed by Fuller, Glenn; Rust, Frederick F.


Book ID
126962480
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
284 KB
Volume
80
Category
Article
ISSN
0002-7863

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Stereoselectivity of the Thermally Initi
✍ Metzger, JΓΌRgen O. ;Blumenstein, Michael πŸ“‚ Article πŸ“… 1993 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 644 KB

Radicals / Addition 1 Stereoselectivity f Alkynes Alkanes can be added to alkynes in a thermally initiated freeradical chain reaction ("ane reaction"). The addition of cyclohexane to 1-alkynes la-1 yields a mixture of (4and (E)-2cyclohexyl-1-alkenes 3a-1. An essential step in this reaction is the ad