Free-Jet Electronic Spectroscopy of the PO 2 Radical
โ Scribed by Lei, Jie; Teslja, Alexey; Nizamov, Boris; Dagdigian, Paul J.
- Book ID
- 126219092
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 79 KB
- Volume
- 105
- Category
- Article
- ISSN
- 1089-5639
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## Abstract Solution and powder ESR spectra of the 4โtrifluoromethylโ1,2,3,5โdithiadiazolyl and 4โpentafluorophenylโ1,2,3,5โdithiadiazolyl free radicals were analysed. Comparison of the ESR parameters with those obtained for the protonated equivalents shows that fluorination produces a drift of unp
A new technique combining supersonic jet expansion and transient frequency-modulation absorption experiments has been successfully developed for spectroscopic investigations of free radicals. The ,~ ~ X transition spectra of NH 2 and HCC1 at near-infrared wavelengths have been obtained using this te