The infrared spectrum of CHCIFz (freon 22, chlorodifluoromethane) in the range of the CH stretching fundamental v, and the two CF stretching fundamentals vj and vs has been measured in a supersonic free jet expansion with rotational temperatures of about 50 K and resolutions up to 0.004 cm-'. The fi
Transient frequency-modulation absorption spectroscopy of free radicals in supersonic free jet expansions
โ Scribed by Bor-Chen Chang; Trevor J. Sears
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 317 KB
- Volume
- 256
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
A new technique combining supersonic jet expansion and transient frequency-modulation absorption experiments has been successfully developed for spectroscopic investigations of free radicals. The ,~ ~ X transition spectra of NH 2 and HCC1 at near-infrared wavelengths have been obtained using this technique for demonstration. In addition, a combination of temporal waveform acquisition and frequency scan using this new technique has produced interesting information on the velocity and density distributions of supersonic jet expansion systems.
๐ SIMILAR VOLUMES
Absorption spectra. fluorescence excitation spectra and fluorescence quantum yields, Y. from the !& manifold of 9.10dichloroanttuacene and anthracene cooled in planar supersonic expansions were simultaneously determined using a pulsed xenon lamp and a monochromator. The dependence of Y from photosel
By means of diode laser spectroscopy we observed signals of \((\mathrm{CO})_{2}\) in a supersonic jet expansion. Nineteen lines of a \(K: 2 \leftarrow 1\) transition were detected by concentration-frequency double modulation in the infrared region. This modulation technique was recently developed in
## Abstract Free radicals are generated in liquid solutions by harmonically modulated photolysis of suitable substrates. Harmonic analysis of the absorbance as functions of wavelength and modulation frequency yields the optical spectra and the decay kinetics of the transient species. The experiment