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Fragmentation of some even-electron nitroaromatic ions: The question of the nitrotropylium ion

✍ Scribed by Robert H. Shapiro; James W. Serum

Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
420 KB
Volume
2
Category
Article
ISSN
1076-5174

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πŸ“œ SIMILAR VOLUMES

Bifunctional even-electron ions. IV. Fra
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As for the corresponding hydroxonium ions, the methoxonium ions R-C(OCH,)-(CH,),-COOCH, (n = 0-5), 6, show as the main reactions those triggered by functional group interaction, but the overall decomposition rate is not much influenced. Loss of CH,OH is the general primary fragmentation, originating

Bifunctional even-electron ions. V. Frag
Bifunctional even-electron ions. V. Fragmentation behaviour of aliphatic hydroxonium ions containing an additional cyano group
✍ U. I. ZΓ‘horszky; P. Schulze πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 710 KB

## The fragmentation behaviour of a series of bifunctional hydroxonium ions C,H,-C(=OH)-(CH,),-CN (n = 0-6), a,, has been investigated by electron impact mass spectrometry. The type of interaction-induced reactions depend strongly on the chain distance between the oxonium and the cyano moiety, but