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Bifunctional even-electron ions. III. Fragmentation behaviour of aliphatic hydroxonium ions containing an additional carbomethoxy group

✍ Scribed by U. I. Záluorszky

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
663 KB
Volume
23
Category
Article
ISSN
1076-5174

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Bifunctional even-electron ions. V. Frag
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## The fragmentation behaviour of a series of bifunctional hydroxonium ions C,H,-C(=OH)-(CH,),-CN (n = 0-6), a,, has been investigated by electron impact mass spectrometry. The type of interaction-induced reactions depend strongly on the chain distance between the oxonium and the cyano moiety, but

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As for the corresponding hydroxonium ions, the methoxonium ions R-C(OCH,)-(CH,),-COOCH, (n = 0-5), 6, show as the main reactions those triggered by functional group interaction, but the overall decomposition rate is not much influenced. Loss of CH,OH is the general primary fragmentation, originating