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Bifunctional even-electron ions. II. Fragmentation behaviour of aliphatic ω-hydroxy and ω-methoxy methoxonium ions

✍ Scribed by U. I. Záhorszky

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
1004 KB
Volume
21
Category
Article
ISSN
1076-5174

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As for the corresponding hydroxonium ions, the methoxonium ions R-C(OCH,)-(CH,),-COOCH, (n = 0-5), 6, show as the main reactions those triggered by functional group interaction, but the overall decomposition rate is not much influenced. Loss of CH,OH is the general primary fragmentation, originating

Bifunctional even-electron ions. V. Frag
Bifunctional even-electron ions. V. Fragmentation behaviour of aliphatic hydroxonium ions containing an additional cyano group
✍ U. I. Záhorszky; P. Schulze 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 710 KB

## The fragmentation behaviour of a series of bifunctional hydroxonium ions C,H,-C(=OH)-(CH,),-CN (n = 0-6), a,, has been investigated by electron impact mass spectrometry. The type of interaction-induced reactions depend strongly on the chain distance between the oxonium and the cyano moiety, but