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Fragmentation of Carbohydrate Anomeric Alkoxyl Radicals. Synthesis of Highly Functionalized Chiral Vinyl Sulfones.

✍ Scribed by Carmen R. Alonso-Cruz; Elisa I. Leon; Francisco J. Ortiz-Lopez; Maria S. Rodriguez; Ernesto Suarez

Publisher
John Wiley and Sons
Year
2005
Weight
31 KB
Volume
36
Category
Article
ISSN
0931-7597

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Fragmentation of Carbohydrate Anomeric A
Fragmentation of Carbohydrate Anomeric Alkoxyl Radicals: New Synthesis of Chiral 1-Fluoro-1-halo-1-iodoalditols
✍ Cosme G. Francisco; Concepción C. González; Alan R. Kennedy; Nieves R. Paz; Erne 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 362 KB 👁 2 views

## Abstract A new general methodology for the synthesis of 1,1,1‐trihaloalditols by starting from 1,5‐anhydro‐2‐deoxy‐hex‐1‐enitol derivatives (glycals) is described. The halogens are introduced sequentially in each of the three different steps of the process. The fluorine is introduced in the firs

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In the Full Paper by Gonzµlez, Suµrez et al., a mistake has been noted. In Table 1, the four structures immediately above entries 21-24 and 25-28 should be replaced with the following structures: The authors apologise for this oversight.