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Fragmentation of Carbohydrate Anomeric Alkoxyl Radicals. A New Synthesis of Chiral β-Iodo Azides, Vinyl Azides, and 2H-Azirines.

✍ Scribed by Carmen R. Alonso-Cruz; Alan R. Kennedy; Maria S. Rodriguez; Ernesto Suarez

Publisher
John Wiley and Sons
Year
2004
Weight
134 KB
Volume
35
Category
Article
ISSN
0931-7597

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Fragmentation of Carbohydrate Anomeric A
Fragmentation of Carbohydrate Anomeric Alkoxyl Radicals: New Synthesis of Chiral 1-Fluoro-1-halo-1-iodoalditols
✍ Cosme G. Francisco; Concepción C. González; Alan R. Kennedy; Nieves R. Paz; Erne 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 362 KB 👁 2 views

## Abstract A new general methodology for the synthesis of 1,1,1‐trihaloalditols by starting from 1,5‐anhydro‐2‐deoxy‐hex‐1‐enitol derivatives (glycals) is described. The halogens are introduced sequentially in each of the three different steps of the process. The fluorine is introduced in the firs

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✍ Cosme G. Francisco; Concepción C. González; Alan R. Kennedy; Nieves R. Paz; Erne 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 58 KB 👁 2 views

In the Full Paper by Gonzµlez, Suµrez et al., a mistake has been noted. In Table 1, the four structures immediately above entries 21-24 and 25-28 should be replaced with the following structures: The authors apologise for this oversight.