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Fragmentation of Carbohydrate Anomeric Alkoxyl Radicals: New Synthesis of Chiral 1-Fluoro-1-halo-1-iodoalditols

✍ Scribed by Cosme G. Francisco; Concepción C. González; Alan R. Kennedy; Nieves R. Paz; Ernesto Suárez


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
56 KB
Volume
14
Category
Article
ISSN
0947-6539

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Fragmentation of Carbohydrate Anomeric A
✍ Cosme G. Francisco; Concepción C. González; Alan R. Kennedy; Nieves R. Paz; Erne 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 362 KB 👁 1 views

## Abstract A new general methodology for the synthesis of 1,1,1‐trihaloalditols by starting from 1,5‐anhydro‐2‐deoxy‐hex‐1‐enitol derivatives (glycals) is described. The halogens are introduced sequentially in each of the three different steps of the process. The fluorine is introduced in the firs

Fragmentation of Carbohydrate Anomeric A
✍ Cosme G. Francisco; Concepción C. González; Alan R. Kennedy; Nieves R. Paz; Erne 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 58 KB 👁 2 views

In the Full Paper by Gonzµlez, Suµrez et al., a mistake has been noted. In Table 1, the four structures immediately above entries 21-24 and 25-28 should be replaced with the following structures: The authors apologise for this oversight.