Fragmentation of 1-aryl-5-(2-dialkylaminovinyl)-1H-tetrazoles upon electron impact
✍ Scribed by Michael Herrmann; Gerhard W. Fischer
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 507 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
✦ Synopsis
The mass spectrometric behaviour of l-aryl-5-(2-dialkylaminovinyl)-lH-tetrazoles was studied, especially l-phenyl-5-(2-dimethylaminovinyI)-lH-tetrazole as a typical example of D-and 'SN-labelled derivatives revealed a rearrangement via a carbodiimide-like intermediate ion.
📜 SIMILAR VOLUMES
## Abstract In this study phenylselenocyanate and some of its derivatives (__o__‐Cl, __p__‐Cl, __p__‐Br, __o__‐NO~2~, __p__‐NO~2~, __o__‐CH~3~, __p__‐CH~3~, __o__‐COOH, __p__‐COOH, __p__‐OCH~3~ substituted) were synthesized (3a–3j). The synthesized compounds were converted to 5‐aryl‐1__H__‐tetrazol
## Abstract The electron impact‐induced fragmentations of 2,3‐dihydro‐1,5‐benzothiazepin‐4(5__H__)‐ones and some related compounds were investigated. On the basis of low‐ and high‐resolution measurements, metastable ion studies by means of mass‐analysed ion kinetic energy spectroscopy and collision