Fragmentation of organosulfur compounds upon electron impact: 2-mercaptoethanol and 1,2-ethanedithiol
β Scribed by Osamu Sekiguchi; Toshiyuki Kosaka; Takeshi Kinoshita; Susumu Tajima
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 459 KB
- Volume
- 145
- Category
- Article
- ISSN
- 0168-1176
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The mass spectrometric behaviour of l-aryl-5-(2-dialkylaminovinyl)-lH-tetrazoles was studied, especially l-phenyl-5-(2-dimethylaminovinyI)-lH-tetrazole as a typical example of D-and 'SN-labelled derivatives revealed a rearrangement via a carbodiimide-like intermediate ion.
## Abstract The electron impactβinduced fragmentation patterns of 2,1βbenzisothiazoline 2,2βdioxide nitro derivatives were studied. The rationalizations proposed for the fragmentations are supported by accurate mass measurements, daughter ion (mass analysed ion kinetic energy and __B/E__ linkedβsca