Isotope effects and H/D scrambling in th
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A. Y.-K. Lau; B. H. Solka; A. G. Harrison
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Article
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1974
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John Wiley and Sons
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English
⚖ 214 KB
The fragmentation reaction [C,(H, D)J+. + [C,(H, D)J+ + (H, D) has been examined in the metastable decomposition region for two pairs of labelled propenes: CH,CD=CH,, CD,CH==CD, and CD,CH=CH,, CH,CD=CD,. The results indicate that complete hydrogen scrambling occurs in the propene molecular ion prior