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Fragmentation isotope effects in the neutralization—reionization of the ethyne-d1 cation

✍ Scribed by Raymond E. March; John G. Macmillan


Book ID
103601273
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
478 KB
Volume
85
Category
Article
ISSN
0168-1176

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Isotope effects and H/D scrambling in th
✍ A. Y.-K. Lau; B. H. Solka; A. G. Harrison 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 214 KB

The fragmentation reaction [C,(H, D)J+. + [C,(H, D)J+ + (H, D) has been examined in the metastable decomposition region for two pairs of labelled propenes: CH,CD=CH,, CD,CH==CD, and CD,CH=CH,, CH,CD=CD,. The results indicate that complete hydrogen scrambling occurs in the propene molecular ion prior