Fragmentation behaviour and ring expansion of 1-methylimidazole and 1-methylpyrazole upon electron-impact
β Scribed by J. van Thuijl; K. J. Klebe; J. J. van Houte
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 521 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The mass spectrometric behaviour of l-aryl-5-(2-dialkylaminovinyl)-lH-tetrazoles was studied, especially l-phenyl-5-(2-dimethylaminovinyI)-lH-tetrazole as a typical example of D-and 'SN-labelled derivatives revealed a rearrangement via a carbodiimide-like intermediate ion.
## Abstract The electron impact mass spectra of 1βphenylβ2βpropenβ1βol and its specifically deuterated analogues have been investigated. Most of the decomposition pathways involve skeletal rearrangements or hydrogen atom transfers, such that a rearrangement of the excited molecular ions of 1βphenyl