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Fractionation of poly bis(p-methylanilino)phosphazene

✍ Scribed by G. Pezzin; S. Lora; L. Busulini


Publisher
Springer
Year
1981
Tongue
English
Weight
296 KB
Volume
5-5
Category
Article
ISSN
0170-0839

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## Abstract Well characterized poly[bis(__p__‐methoxyphenoxy)phosphazene] (PB(4‐MeO)PP) has been investigated employing X‐ray diffraction and differential scanning calorimetry (DSC). The DSC heating scan of the original PB(4‐MeO)PP specimen exhibits one exotherm at 110Β°C and two endotherms at 106Β°C

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ANtraet--By reacting iodine with poly[bis(p-tolylamino)]phosphazene (PTAP) in methylene chloride, a doped material is obtained; imino side-groups of the macromolecule are complexed to form "inner'" charge-transfer structures. This process is accelerated by irradiating the system with light of a suit