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Single-crystal poly[bis(p-fluorophenoxy)phosphazene] (PBpFPP)

✍ Scribed by Toru Masuko; Makoto Hoshi; Jun Kitami; Koichiro Yonetake

Publisher
Springer
Year
1988
Tongue
English
Weight
233 KB
Volume
7
Category
Article
ISSN
0261-8028

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## Abstract Well characterized poly[bis(__p__‐methoxyphenoxy)phosphazene] (PB(4‐MeO)PP) has been investigated employing X‐ray diffraction and differential scanning calorimetry (DSC). The DSC heating scan of the original PB(4‐MeO)PP specimen exhibits one exotherm at 110Β°C and two endotherms at 106Β°C

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The crystal structure and chain conformation of polyibis(3,4-dimethylphenoxy)phosphazene] -PB(dMe)PP -have been studied by X-ray diffraction techniques. The unit cell of this polymer shows an orthorhombic form with the crystallographic parameters a=2.05, b= 1.49, c (chain axis) =0.998 nm. Its space