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Fourier transform emission spectroscopy of CoCl in the 500 nm region

✍ Scribed by T. Hirao; B. Pinchemel; P.F. Bernath

Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 180 KB
Volume: 219
Category: Article
ISSN: 0022-2852
DOI: 10.1016/s0022-2852(03)00020-1

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✦ Synopsis

Fourier transform emission spectra of CoCl were obtained with a tube furnace-DC discharge source in the 450-500 nm spectral region. In addition to observing two different band systems, which were assigned as [20.7] Mol. Spectrosc. 212 (2002) 111], we obtained data for additional sub-bands and vibrational levels. In contrast to the previous work, intense Q branches are seen in the [21.3]-X 3 U 4 bands which indicate that these bands are likely DK 6 ¼ 0 transitions. The equilibrium rotational constant B e for the ground X 3 U 4 state is 0.1801104(28) cm À1 , the equilibrium bond length is 2. 065122(16)

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Fourier transform emission spectroscopy of CoCl in the 500&#xa0;nm region

✦ Synopsis

Fourier transform emission spectroscopy of CoCl in the 500 nm region