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High-Resolution Fourier Transform Emission Spectroscopy of the TiCl Radical in the 420-nm Region

✍ Scribed by Takashi Imajo; DongBing Wang; Keiichi Tanaka; Takehiko Tanaka

Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 308 KB
Volume: 203
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.2000.8184

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✦ Synopsis

Emission spectra of the TiCl radical in the 420-nm region have been observed at a resolution of 0.04 cm Ϫ1 using a Fourier transform spectrometer. A new electronic assignment of 4 ⌫-X 4 ⌽ has been proposed. Rotational analysis has been provided for the 0 -0 and 1-1 vibrational bands of the 4 ⌫ 5/ 2 -X 4 ⌽ 3/ 2 and 4 ⌫ 7/ 2 -X 4 ⌽ 5/ 2 spin components and the 0 -0 band of 4 ⌫ 9/ 2 -X 4 ⌽ 7/ 2 .

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