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Formation of XeF* excimers in the process of energy transfer from excited nitrogen molecules to XeF2

✍ Scribed by A.M. Pravilov; L.G. Smirnova; A.F. Vilesov

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 447 KB
Volume: 187
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(91)90411-2

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✦ Synopsis

Emission of XeP( B, C) excimers was observed when XeF, was added to active nitrogen. This indicates XeP formation in the process of dissociative electronic energy transfer from NT to XeFI: N: + XeF 1 *XeF*+ N2 + F. The termolecular rate constant for XeF encitation in active nitrogen has been measured to be 1O-'4 cm6 s-l. The formation of XeP in the reaction Xe*({6s}) + XeF+XeP+ Ft Xe was observed and the yield of Xep excitation is estimated to be 0.5.

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