Formation of stable σ-aryliron(III) complexes from the reaction of chloroiron(III) octaphenyltetraazaporphyrinate with aryl Grignard reagents
✍ Scribed by Pavel A. Stuzhin; Ol’ga V. Mal’chugina; Stanislaw Wolowiec; Lechoslaw Latos-Grazynski; Boris D. Berezin
- Book ID
- 111730088
- Publisher
- Royal Society of Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 210 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0959-9436
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## Abstract Addition of aryl Grignard reagents to an iron(III) tetraphenylporphyrin π cation radical, [(TPP⋅)Fe^III^Cl] (SbCl~6~), in dichloromethane solution at 202 K yields a mixture of σ‐phenyl iron(IV) tetraphenylporphyrin, [(TPP)Fe^IV^(Ph)] (SbCl~6~), and σ‐phenyl iron(III) tetraphenylporphyri
Asymmetric reductions with the Grignard reagent from optically active lchloro-2-phenylbutane have been studied by Mosher and coworkers. (1) We wish
Th8 competitive addition-reduction of 2,kdlmethyl-3-pento rith %.PrHgRra vas studied using the procedure described earlier'. The reaction vas followed by quantitative vapour pba8e chromatogra phY2 analysis of the products. The Grlgnard reagent was prepared by reaction of n.propylbromlde vlth magne-