The Grignard reagent from racemic l-chloro-2-phenylbutane has been partially resolved by allowing it to react with less than one equivalent of one of several readily available chiral ketones. Reaction with approximately 0.5 equivalents(2) of (+)-camphor, (-)-fenchone, (-)-menthone or (+)-3-methylcyc
✦ LIBER ✦
Asymmetric organic reactions, III. Reactions of diastereomeric ether complexes of the grignard reagent from (t)-1-chloro-2-phenylbutane
✍ Scribed by James D. Morrison; Robert W. Ridgway
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 153 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Asymmetric reductions with the Grignard reagent from optically active lchloro-2-phenylbutane have been studied by Mosher and coworkers. (1) We wish
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## Abstract The solvolysis of __cis__(chloro)(1‐amino‐propan‐2‐ol)bis(ethylenediamine)cobalt(III) in aqueous alcoholic media using methanol, propan‐2‐ol, __t__‐butanol as cosolvents, resulted in the formation of the (N,O) chelated product__cis__[Co(en)~2~(NH~2~CH~2~CHOHCH~3~)]^3+^. The pseudo first