The fluoride ion-induced rearrangement of Ph (ClCH,)SiH, was expected to provide either Ph-MeSiHF (migration of hydride) or (PhCH2)SiH2F (migration of phenyl). However, when B u $ I f F -(commercial TBAF) is added to Ph(ClCH2)SiH2, a mixture of fluorine-terminated siloxanes, FPh-MeSiO(PhMeSiO)&MePhF
Formation of SiH3+ions in reactions of small hydrocarbon ions with SiH4
✍ Scribed by G. Bano; A. Luca; J. Glosík; P. Zakouřil; W. Lindinger
- Book ID
- 105720966
- Publisher
- Springer
- Year
- 2000
- Tongue
- English
- Weight
- 151 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0011-4626
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The reaction of SiH4 with active nitrogen in a discharge-flow system was found to produce strong chemiionization besides the well-known SiN\* and Si\* chemiluminescences. In the presence of a large initial excess of N atoms, both N and SiH4 disappeared completely in the course of the reaction. Addit
Gas-phase reactions of 1,2,3,4,5-pentamethylcyclopentadiene (HCp\*) with three actinide ions, Np ϩ , Pu ϩ , and Am ϩ , were studied by laser ablation mass spectrometry. The primary goal was to determine if an unusual, non-insertion mode of C-H activation reported for lanthanide ions, Ln ϩ , with thi